Vibronic Analysis for B̃ - X̃ Transition of Isopropoxy Radical
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منابع مشابه
Rotationally resolved B̃←X̃ electronic spectra of the isopropoxy radical: A comparative study.
The B̃-X̃ laser-induced-fluorescence spectrum of jet-cooled isopropoxy radical (i-C3H7O[middle dot]) has been recorded. Using an isolated state model the observed rotational and fine structure of the origin band has been well simulated to determine rotational constants for both the X̃ and B̃ states and the electron spin-rotation constants of the X̃ state. The line intensities are well simulated with...
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The recent cavity ringdown (CRD) measurement of the forbidden à 2E ← X̃ A2 transition of the nitrate radical NO3 reveals a rich, well-resolved spectrum in the near-infrared. The spectroscopic detail provides a new window onto the Jahn–Teller (JT) and pseudo-Jahn–Teller (PJT) effects in NO3. This paper reviews the current experimental evidence for vibronic coupling in the à state and discusses th...
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Spectra of ã B1(n1n2n3)5(110) and (200) – X̃ A1(000) of SO2 and SO2 are obtained in a supersonic jet at a resolution 0.015 cm. The rotational structures are analyzed for both isotopic species to obtain precise rotational and spin constants. Two new bands at 27 032.222~1! and 27 515.41~1! cm arising from vibronic interaction separately with vibrational state ~110! and ~200! of ã B1 are assigned t...
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تاریخ انتشار 2013